When you have a model that describes the required situation well enough so that you can use scientific laws to calculate the probabilities of the outcomes of the experiment.
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empirical probability is when you actually experiment with it and get data values, and theoretical probability is when you use math to make an educated guess.
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As the number of times that the experiment is conducted increases, the experimental probability will near the theoretical probability - unless there is a problem with the theoretical model.
Theoretical probability:Theoretical probability is when you decide what is the probability of something using the information that is given to you!
Theoretical probability- what the probability "should be" if all outcomes are equally likely.