It could be the capacity of a coffee cup.
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tea in a cup
Yes, I would use milliliters.
Liters (Most European and Asian countries quote capacity of refrigerator in liters)
If you want to measure the length of a spoon, you'd use centimeters or millimeters. If you want to measure its capacity (how much it could hold), you'd use milliliters.
Milliliters is the metric unit to use for the capacity of a thimble.