Archimedes
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The value of pie calculated by first Indian scientist Baudhayana
Archimedes (287-212 BC) was the first to have had a serious attempt at calculating pi.
The ancient Babylonians from around 1700 BC used pi = 3.125. The name of the person who calculated that value was not recorded.
pi is endless! Edit: The value of Pi has so far been calculated to more than two million places.