Archimedes (287-212 BC) was the first to have had a serious attempt at calculating pi.
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The value of pie calculated by first Indian scientist Baudhayana
Archimedes
The ancient Babylonians from around 1700 BC used pi = 3.125. The name of the person who calculated that value was not recorded.
aryabhatta.
The Egyptians calculated the area of a circle by a formula that gave a aproximate value of 3.1605