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The experimental probability of anything cannot be answered without doing it, because that is what experimental probability is - the probability that results from conducting an experiment, a posteri. This is different than theoretical probability, which can be computed a priori. For instance, the theoretical probability of rolling a 3 is 1 in 6, or about 0.1667, but the experimental probability changes every time you run the experiment
Experimental errors would cause the experimental value of specific heat capacity to be higher than the standard value.
theoretical probability can be smaller than expiremental like this say you toss a coin 4 times it lands on head 3 times that means the theoretical 1/2 is now smaller than the expiremental 3/4
yes
They are generally agreed to be theoretical and experimental probabilities. Probability is probability. The concept may be applied to any causal event which has more than one potential outcome.