The rigidity of the triangle derives from the fact that you cannot change any angle in a triangle without also changing the length of at least one side; in any other type of polygon, it is possible to alter the angles of the polygon without changing the lengths of the sides. So if you have a physical object in the form of a triangle, the sides are not going to change their length unless you break them. Other shapes can fold up, but triangles won't.
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The most rigid shape that you can make out of straight pieces is the triangle.
triangle
A polygon with any number of sides can have a 156 degree angle, as can most non-polygonal plane shapes.
Square
most likely a triangular prism