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It is because the index is related to the velocity of light in air (ideally vacuum) and the medium in question. Since the velocity of light in vacuum is greater than it can be in any other media, the index of refraction of these other media relative to the vacuum is greater than 1.

However, if you studied light travelling through glass and then water, the index of refraction between those two would be 0.89 (approx).

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Q: Why the index of refraction is greater than to one?
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