There are only three regular polygons which with tile. These a re a triangle, quadrilateral (square) and hexagon.
This is because if there are n tiles meeting at a point, then the sum of the angles around that point must be 360 degrees - otherwise the polygons will overlap. The only regular polygons with interior angles that are factors of 360 are the ones mentioned above.
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A regular polygon will tile it if its internal angle divides 360 degrees.
Not always
Not by itself.
Yes, but only with some polygons.
A 6 sided hexagon polygon can be regular or irregular.