Yes, Quebec is the largest province at 1.542 million km². Nunavut is the largest territory at 2.093 million km².
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ontario is the most populated (nearly 14 million) Although quebec is the largest province, the territory of nunavut has much more land area. so technically it is quebec in terms of being a province, if you include territories however, it is nunavut.
The largest Canadian province in terms of population is Ontario. Based on the 2006 Statistics Canada census, the population of Ontario was 12,160,282 that year. The largest Canadian province in terms of land mass is Quebec. Taken from the 2006 census, Quebec's land area is 1,356,366.78 square kilometres. Note: Nunavut is a Canadian territory, not a province, that has a land area of 1,932,254.97 square kilometres and a population of 29,474 inhabitants in 2006.
NU is the biggest Territory in canada, it's not a province. QC is the biggest province. ON is second and BC is third in total area. If you just count land area and subtract the freshwater, BC and ON switch places. PEI is the smallest province.
Quebec
Quebec is the largest land wise but Ontario has the most people.