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assuming you mean a standard cubic foot of air

1 scf = 1 cu.ft. of air at 60F at 14.696 psia at sea level

assuming the tank of air is at 60F and at 1 atmosphere ambient pressure and 60F ambient temperature

then the equation V = P'V'/P is used to determine the volume of air compressed into the tank

so:

V = (125 psig + 14.696psia)(5gal x 230.9 cu.in./gal./1728 cu.in./cu.ft.)/14.696psia

V = (139.696 psia)(.66811 cu.ft)/14.696 psia

V = ~6.350 standard cu. ft. of air compressed into the tank

* a change in ambient temperature, tank temperature, tank pressure or atmospheric pressure will change the actual volume of air compressed.

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