That depends on the type material you are referring to. Also, these are two different types of measurements. One is volume the other is weight or mass. Please edit your question to include more context or details.
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There are approximately 8.34 pounds in one gallon of water. However, the weight of a gallon can vary depending on the substance being measured.
Approximately 8.6 pounds of beef equal one gallon in volume.
One gallon of liquid beeswax weighs approximately 8.5 pounds.
About 8.35 pounds for one US gallon of water.
One gallon of medium invert sugar typically weighs around 10 pounds.
Burning a gallon of gasoline emits approximately 20 pounds of CO2.