No.
To elaborate, the smallest regular polygon, an equilateral triangle, has 60 degree interior angles. The next larger one, a square, has 90 degree interior angles. In fact, for any regular polygon, the interior angles measure 180*(n-2)/n degrees, where n is the number of sides. No polygon has less than 3 sides. Thus, no regular polygon can have interior angles less than 60 degrees.
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There is no such regular polygon with 45 degree interior angles; the smallest interior angles in regular polygons are 60 degrees, which is found in a triangle.
The measure of the entire interior of a regular decagon is 1440 degrees. 1440 divided by 10 equals 135 degrees. Therefore, 135 degrees is your final answer.
45 degrees
The tessellating polygons must meet at a point. At that point, the sum of the interior angles of the polygons must 360 degrees - the sum of angles around any point. Therefore, each interior angle must divide 360 evenly. The interior angles of regular polygons with 7 or more sides lie in the range (120, 180) degrees and so cannot divide 360.
Each interior angle measures 135 degrees