PN is pressure rating of pipe. the number gives you the resistance against pressure. ın that case it is 10 bar.
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10"size and 25bar pressure
Pressure Nominal 40; 40 bar pressure rating for European flange
Angle MPN
the power of 10 mean 10 100 1,000 100,000 the power of 10 mean 10 100 1,000 100,000
angle P