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54
54/60 = 9/10
46/54 = 23/27; as there is now a prime number in the fraction, that is its simplest form.
Assuming you meant 4 54/100 then NO the simplest form is 4 27/50.
Expressed as a proper fraction in its simplest form, 54% is equal to 27/50 or twenty-seven fiftieths.