It is a triangle, and it will be the same all the way through the prism.
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Triangular
A right-angled triangular prism!
No, a triangular prism cannot roll because it does not have a circular cross-section like a cylinder or a sphere. Rolling requires a continuous curved surface that can rotate around an axis. A triangular prism has a polygonal cross-section with flat sides, so it would slide rather than roll.
Volume of a triangular prism = cross-section area times length
A prism has the same cross section throughout its length no matter what form it may take i.e. a cubic prism, a cuboid prism, a triangular prism, a hexagonal prism, a cylindrical prism etc.