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Significant Figure.
0.320g has three significant figures. A significant figure is any non-zero digit or any embedded or trailing zero. Leading zeros are not significant.
unit
0.1020 is a number to 4 significant figures. The rule is that "Zeros must be kept to show the position of the decimal point or to indicate that zero is a significant figure." Then the leading zero before the decimal point is retained as this shows the position of the decimal point. The zero between 1 and 2 is a key part of the number. The final zero (after 2) is a significant figure otherwise the number would be written 0.102. Consequently, the 4 significant figures are "1020" but are presented as 0.1020 to ensure the true value of the number is accurately given.
It is in the hundreds' place so its value is 700.