Experimental errors occur when the performer of experiment make a mistake.
now Performer may be a human or it can be a machine or any apparatus and mistake may be of intentional, Conventional or mistake by mistake.
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An experimental error is is
You carry out the experiment a large number of times. Count the number of times it was carried out (n). Count the number of times in which the particular outcome occurred (x). Then, the experimental probability for that even is x/n.