A 1 in 6 chance.
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4 out of 12 chances if each dice had 6 sides. 2 out of 6 chances to simplify it.
Assuming you are rolling a six-sided dice, it is 1/3 for one dice and 2/3 for two dice.
When rolling one die, the probability of getting a 4 is 1 in 6, or 0.1667. If two dice are rolled, you get two unrelated chances of rolling at least one 4, so the probability is 2 in 6, or 0.3333.
The only way to get a 12 is to get two sixes. The chance of rolling a six is 1/6 and chance of rolling two sixes is 1/36 or about 2.78%
The probability of rolling doubles with two dice is 1 in 6, or about 0.167.