None, the Number Pi is nothing to do with seconds (time).
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pi has no ending number so the mathematician used the three first number which is 3.14 to present for pi but it is not = 3.14, it is approximately (~ 3.14)
there are 2 pi bonds and 1 sigma bond in propyne (alkynes)
YES! the number pi is endless
(pi) itself is an irrational number. The only multiples of it that can be rational are (pi) x (a rational number/pi) .
Pi is irrational.