The base of a prism can be any polygon, but the polygon face parallel to the base must be congruent.
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That depends on the shape of the base. A prism can have any sort of polygon for its base.
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No. Polyhedra are three-dimensional objects, and the base of any prism, strictly speaking, should be two-dimensional. Any convex polygon (which is two-dimensional) can form the base of a pyramid. A circle, which is technically not a polygon, is the only convex two-dimensional figure that cannot form the base of a pyramid because it forms the base of a cone.
No, a prism has flat sides. Triangular prisms are very common, but any polygon can be the cross section of a prism.
Any face that is not a base is a what