Brix measures total dissolved solids while Total sugar is only a measure of sugar content. Higher sugar content will raise the brix measurement, but higher brix measurement does not always mean there is a higher sugar content.
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Brix is a measurement of the mass ratio of dissolved sugar to water often shown as °Bx. It is a way of finding out the sweetness of fruit by measuring the natural sugars.
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The hydrometer measures specific gravity, which is a unit-less quantity that expresses the ratio of a liquid's density to the density of water. For example, if a liquid as an SG of 1.000, it has the same density as water. An SG of 1.100 indicates that a liquid is ten percent denser than water. One with an SG of 1.010 is just one percent denser. On some hydrometers there are other scales whose units are in degrees Brix, degrees Balling, or Plato. But those units are used specifically to measure sugar content in juices, wine, and beer. If you're curious about that, Wikipedia has a few articles to check out.
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