Theoretical articles use existing research to advance theory. The development of theory is traced in order to expand and refine theoretical constructs.
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What determines the theoretical throughput of a bus
Theoretical: pertaining to, or consisting in theory
Theoretical probability- what the probability "should be" if all outcomes are equally likely.
As the number of times that the experiment is conducted increases, the experimental probability will near the theoretical probability - unless there is a problem with the theoretical model.
Empirical anything is what is observed. Theoretical is a calculation of what things ought to be.