The complement of an event occurring is that it does not occur.
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"one third" is not an event and so cannot have complement nor a probability.
With the information that is available from the question, it is impossible.
The complement involves probability. Say the probability of choosing a red marble was 3/10. So the complement, or the chance of not choosing a red marble is 7/10. Think of it as the opposite of the probabilty. You simply subtract the numerator from the denominator and you have the complement. (10-3=7 in this case, then you would put your difference over the probabilities denominator, so it would be 7/10.)
Read the introduction to probability and probability measures at StatLect.com
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