The chance is 9%
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The probability of not rolling a sum of six with two fair dice is 1 minus the probability of rolling a sum of six. There are 36 permutations of rolling two dice. Of these, five sum to six, 1+5, 2+4, 3+3, 4+2, and 5+1. The probability, then of rolling a sum of six is 5 in 36. The probability, then of not rolling a sum of six is 31 in 36, or about 0.8611.
If its a fair dice 1/6
The probability of rolling a 9 with two dice is 4/36 or 1/9. There are 36 possible combinations and a 9 is obtained by rolls of 3,6; 4,5; 6,3; & 5,4.
1 in 6.
The probability of rolling either a 6 or 4 on one roll of a dice is two thirds (one sixth plus one sixth because both four and six have a probability of one sixth.