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It is not clear what the dimensions are. A triangular prism is normally specified by four lengths: the three sides of the triangular base(s) and one for the length. However, the question contains 5 lengths!
The volume is pi x diameter squared times height//4 The volume collected is 5mm x 100 mm x 100 mm x 3.14/4 = 39250 cu mm = 39.25 cu cm keep in mind that the rain measurement is still 5mm independent of volume collected.
125 mm3 = 0.125 cm3
5mm is half a cm
the volume of the box is 1