If you're only rolling one die, it's a probability of 1 out of six, or 16.67%.
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Rolling it once there is a 1 out of 6 chance - because there is 6 numbers on a dice and one of them is three. so rolling it twice would be a 2 out of 12 chance / 0.16 / 16% chance
If it is a regular dice then the probability is 3/6 that is 1/2
The probability for dice depends on how many. For a die, it is 1/3.
The probability of not rolling a sum of six with two fair dice is 1 minus the probability of rolling a sum of six. There are 36 permutations of rolling two dice. Of these, five sum to six, 1+5, 2+4, 3+3, 4+2, and 5+1. The probability, then of rolling a sum of six is 5 in 36. The probability, then of not rolling a sum of six is 31 in 36, or about 0.8611.