For a 200amp service you need number 4 copper
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The wire used to ground a water pipe typically needs to be a minimum of 10 AWG copper wire. It's always best to consult with local building codes or a licensed electrician to ensure that the proper size wire is used for grounding.
The size of the ground wire for a circuit is typically based on the size of the circuit breaker protecting that circuit. For a 200 amp circuit breaker, the recommended ground wire size is 4/0 AWG (American Wire Gauge) copper wire. This wire size helps ensure that the ground wire can safely carry any fault currents that may occur in the electrical system.
In the CEC, if pipe fill is used using table 6, ground wires are not included in the count. If pipe fill is used using cross sectional area of conductors and pipe then the ground wire must be included along with the current carrying conductors. A continuous metallic conduit system is considered a ground return path for fault currents.
The ground wire in a two or three conductor #12 cable is a #14 bare ground wire.
For a 20 amp circuit, a 12-gauge copper ground wire is typically recommended. This wire size can safely handle the current and provide proper grounding for the circuit.
1/0 copper