Most mathematicians use "100-gon." If you want to show off, use hectogon or centagon.
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Centigon would have to be the name of a shape with 100 sides. There is no official name but you would use the prefix of the number, which in this case is "centi-".
a shape with equal sides
A shape with four sides has four vertices and a shape with three sides has three vertices, so a shape with four sides has more vertices than a shape with three sides.
The Shape That Has 8 Sides Is A Octagon Which Has 8 Equal Sides
shape no pairs of perpendicular sides