Oh, isn't that a happy little question! Yes, 23 is a Prime number, which means it is only divisible by 1 and itself. So, it is relatively prime to any other number that is not a multiple of 23. Just like how every tree in our painting is unique and special in its own way.
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One number, by itself cannot be relatively prime - or otherwise. Relative primality is a property of two (or more) numbers.