Infinitely many.
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There are an infinite number of 3d shapes with more than 20 faces.
dodecahedron
A cube has 8 vertices and 6 faces. Therefore a cube has 2 more vertices than faces.
A pyramid can have 0 or 1 square faces. It can have 4 or more faces - there is no limit.
It's more of a term than a single word. But it is the little shapes on the ice when it freezes.