There are an infinite number of 3d shapes with more than 20 faces.
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dodecahedron
Infinitely many.
anything that has more than nine sides is called the number of faces, in this case 20, with agon added to it. so a figure with twenty faces or sides is called a twentyagon.
It's more of a term than a single word. But it is the little shapes on the ice when it freezes.
Bipyramids are a class of polyhedra with more faces than vertices.