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The theoretical probability provides a model for predicting the outcome of trials. You then carry out a number of trials. Compare the outcome of your trials with the results predicted by the theoretical model. The comparison will usually involve "hypothesis testing", a branch of statistics. This is a method to test how likely the actual outcomes are if the theoretical probabilities were true. The exact nature of the test will depend on the theoretical basis and so the answer cannot be simplified.
What determines the theoretical throughput of a bus
Theoretical: pertaining to, or consisting in theory
Theoretical articles use existing research to advance theory. The development of theory is traced in order to expand and refine theoretical constructs.
Theoretical probability- what the probability "should be" if all outcomes are equally likely.