It depends on the petroleum. Petroleum is a mixture that varies from one area to another.
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how do I label the first part of the fraction bar with the correct unit fraction
To divide a fraction by a fraction, multiply the first fraction by the reciprocal of the second one.
Multiply the first fraction by the reciprocal of the second. That is, flip the second fraction over and then multiply the two.
numerator
823 is a proper fraction since it has no decimal.