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Standard deviation in statistics refers to how much deviation there is from the average or mean value. Sample deviation refers to the data that was collected from a smaller pool than the population.
What is the sample mean?
Suppose the mean of a sample is 1.72 metres, and the standard deviation of the sample is 3.44 metres. (Notice that the sample mean and the standard deviation will always have the same units.) Then the coefficient of variation will be 1.72 metres / 3.44 metres = 0.5. The units in the mean and standard deviation 'cancel out'-always.
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Did you mean, "How do you calculate the 99.9 % confidence interval to a parameter using the mean and the standard deviation?" ? The parameter is the population mean μ. Let xbar and s denote the sample mean and the sample standard deviation. The formula for a 99.9% confidence limit for μ is xbar - 3.08 s / √n and xbar + 3.08 s / √n where xbar is the sample mean, n the sample size and s the sample standard deviation. 3.08 comes from a Normal probability table.