No.
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No, methane (CH4) does not have any lone pair electrons around the central carbon atom. Each hydrogen atom shares one electron with carbon in a single covalent bond.
nitrogen aton in NH3 has one lone pair of electron
Nitrogen trifluoride (NF3) has one lone pair of electrons on the nitrogen atom.
A lone pair- as the name suggests is a pair of electrons which has not yet been shared with any other atom
lone pair has more electrons than bond pair
iron has unpaired electrons. the term 'lone pair' is not used for metals