Assuming you're talking about standard six-sided dice numbered 1-6, the least likely rolls are 2 and 12, each of which should come up 1 time in every 36 rolls on average.
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It is 4/11.
It is 0.8181... recurring.
1 in 6.
Rolling one die, it is 1/6. Rolling two dice, it is 2/6, which can be simplified to 1/3 or 33.33%.
2